Other topics include: photoelectron, spectroscopy and magnetic resonances introduction to statistical thermodynamics including partition functions and calculations of various thermodynamics properties, equilibrium constants and rate constants. The course deals with the characterization of patterns of molecular quantized energy levels in rotational, vibrational and electronic spectra of both linear and non-linear molecules. Three credits and lab/tutorial.ģ32 Introduction to Molecular Spectroscopy and Statistical Thermodynamics The topics covered are: the postulates of quantum mechanics and their applications to simple physical systems, including particle in a box the quantum mechanical model for vibration and rotation of molecules the hydrogen atom and many electron systems introduction to the Variation Principle and Hückel’s molecular orbital method. The course deals with quantum mechanics and its applications to the structure of atoms and molecules. Required for the first term of the junior year. Required for, and restricted to, students in degree programs where chemistry is Science A. Use will be made of spectral data correlation charts, compilations and databases. While the theory and instrumentation of each technique will be presented, the course will focus on the interpretation of spectral data to provide information on functional groups, bonding, and stereochemistry. Methods for deducing the structural features of organic compounds will be examined, with a major emphasis on the use of spectroscopic techniques. Some more complex special cases, including purine and pyrimidine systems, will also be included. Synthesis, structural aspects, and chemical properties of these compounds will be examined. The course consists of a survey of aromatic compounds, focusing mainly on aromatic heterocycles containing one or two heteroatoms. A continuation of CHEM 220 which includes: addition and condensation polymerization, including some kinetics divalent carbon compounds (carbenes) pericyclic reactions Woodward Hoffmann rules mass spectrometery of organic compounds organic chemistry of sulfur, phosphorous, and silicon compounds carbohydrates, amino acids, proteins, lipids dyes and dyeing mechanisms of nucleophilic substitutions.
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